From: Wear-resistant surface coloring by ultrathin optical coatings
Materials | Hardness [49] | Evaluated thin-film Mohs hardness by scratch tests. |
---|---|---|
Metallic coatings | angle-independent | Yes |
Au | 2.5-3 | <1.5 (30-nm-thick on c-Si, <10B pencil) |
Al | 2.5-3 | <3 (30-nm-thick on c-Si, 5H pencil) |
Cu | 3 | <3 (30-nm-thick on c-Si, 4H pencil) |
Pt | 3.5 | ∼3 (30-nm-thick on c-Si, 10 H pencil) |
TiN | 9 | 7-9 (50-nm-thick on sapphire, >quartz; <sapphire) |
Semiconductor coatings | angle-independent | Yes |
Ge | 6 | <3 (30-nm-thick on sapphire, 8H pencil) |
Si | 6-7 | <3 (30-nm-thick on sapphire, 8H pencil) |
TiAlN | 9 | 7-9 (50-nm-thick on sapphire, >quartz; <sapphire) |
Dielectric coatings | angle-independent | No |
AlN | 9 | 7-9 (100-nm-thick on glass, >quartz; <sapphire) |
Bragg coatings | angle-independent | No |
Multilayer dielectrics | ∼ | 5.5-6.3 (6.5 μm on glass, <stainless steel) |
SM-type coating | angle-independent | Yes |
Si(50nm)-Au(50nm) | ∼ | <2 (substrate: Si wafer, 6B pencil) |
Ge(50nm)-Au(50nm) | ∼ | <2 (substrate: Si wafer, 6B pencil) |
Si(50nm)-Cu(50nm) | ∼ | <2.5 (substrate: Si wafer, 3H pencil) |
Si(50nm)-Al(50nm) | ∼ | <2.5 (substrate: Si wafer, 4H pencil) |
Si(50nm)-Ag(50nm) | ∼ | <2.5 (substrate: Si wafer, 4H pencil) |
Si(50nm)-Pt(50nm) | ∼ | <3 (substrate: Si wafer, 8H pencil) |
Si(30nm)-TiN(50nm) | ∼ | <3 (substrate: Si wafer, 9H pencil) |
TiAlN(30nm)-TiN(50nm) | ∼ | 7-9 (substrate: Si wafer, >quartz; <sapphire) |
FROC-type coating | angle-independent | Yes |
TiAlN-TiN-AlN-TiN | ∼ | 5.5-6.5 (130-nm-thick on sapphire, >glass; <c-Si) |